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THE AMMONIA WORKS

Haber Process Lab

Make a prediction. Change a condition. Find the compromise.

N₂ + 3H₂ ⇌ 2NH₃All gases · Forward reaction releases heat
INSIDE THE REACTOR

A reversible reaction, in motion

Nitrogen atomsHydrogen atoms

Shapes show N₂, H₂ and NH₃. Each represents a share of the gas; the display is not a literal molecule count or collision simulation.

Nitrogen currently in NH₃0%
Equilibrium target

Percent of the nitrogen atoms in this mixture that are in ammonia. For a fresh 1:3 N₂:H₂ feed, this also equals nitrogen conversion.

CHANGE ONE CONDITION
250 °C650 °C
50 bar300 bar

Start with the compromise

Try lowering the temperature: watch the equilibrium target rise while the response becomes slower.

Disturb the mixture

Temperature and total pressure stay controlled. The chamber adjusts volume as the gas amount changes.

FOLLOW THE CHANGE

Mixture vs equilibrium target

● Mixture┄ Target

Illustrative model time, not real reactor seconds. Each condition change starts a new trace. The dashed line is the equilibrium target, not a reaction rate.

The science behind this model

N₂(g) + 3H₂(g) ⇌ 2NH₃(g), ΔH ≈ −92 kJ per reaction as written. The forward reaction is exothermic. An iron catalyst provides a lower-activation-energy pathway for both directions; it changes the speed, not the equilibrium position.

The equilibrium calculation uses ideal-gas partial pressures at controlled temperature and total pressure, with a 1 bar standard state. It uses a fixed-enthalpy van ’t Hoff approximation and an illustrative reference K = 1.01 × 10⁻⁵ at 450 °C. Real high-pressure gases are nonideal: these percentages are learning-model outputs, not factory predictions.

Response speed is an illustrative temperature-dependent relaxation towards equilibrium. It is not a measured kinetic law. At equilibrium forward and reverse reactions still occur; equal rates do not mean equal gas amounts. Particle motion is illustrative.

The starting 450 °C and 200 bar illustrate the familiar classroom compromise. Industrial conditions vary with catalyst and plant design. The notebook compares ideal equilibrium conversion for fresh feed, not actual single-pass throughput or whole-plant yield.

Sources: OpenStax: shifting equilibria · University of York: ammonia manufacture. Continue with reversible reactions and equilibrium.