FC
Reactivity 1.3 Flashcards
Active Recall for Energy from Fuels
Flashcards: read all 12 questions and answers
- Name the three fossil fuels.Coal, petroleum (crude oil), and natural gas. All are non-renewable hydrocarbons.
- What is produced in incomplete combustion?Carbon monoxide (CO) and/or carbon (soot/particulates) along with water. Less energy is released.
- Why is CO dangerous?Carbon monoxide binds with very high affinity to haemoglobin, displacing oxygen and preventing oxygen transport. It is colourless and odourless.
- How is SO₂ produced from fuels?From sulphur impurities in fossil fuels. SO₂ dissolves in rainwater to form sulphurous/sulphuric acid (acid rain).
- Define specific energy.Energy released per unit mass of fuel (kJ kg⁻¹ or MJ kg⁻¹).
- Define energy density.Energy released per unit volume of fuel (kJ dm⁻³).
- Which fuel has the highest specific energy?Hydrogen (approximately 142 MJ kg⁻¹), but it has very low energy density by volume because it is a gas.
- How is bioethanol produced?By fermentation of sugars (from sugarcane/corn) using yeast: C₆H₁₂O₆ → 2C₂H₅OH + 2CO₂
- What is transesterification?The reaction of vegetable oils/fats with methanol (+ base catalyst) to produce biodiesel (FAME) and glycerol.
- Are biofuels truly carbon neutral?In theory yes (CO₂ absorbed in growth = CO₂ released in combustion), but in practice NO - farming, processing, and transport all require energy.
- Write the half-equations for a hydrogen fuel cell.Anode: H₂ → 2H⁺ + 2e⁻ | Cathode: O₂ + 4H⁺ + 4e⁻ → 2H₂O | Overall: 2H₂ + O₂ → 2H₂O
- Give two disadvantages of hydrogen fuel cells.1. Difficult to store H₂ (low energy density by volume, needs high pressure or cryogenic tanks). 2. Most H₂ is currently made from fossil fuels (steam reforming).