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Reactivity 1.3 Flashcards

Active Recall for Energy from Fuels

Flashcards: read all 12 questions and answers
  1. Name the three fossil fuels.
    Coal, petroleum (crude oil), and natural gas. All are non-renewable hydrocarbons.
  2. What is produced in incomplete combustion?
    Carbon monoxide (CO) and/or carbon (soot/particulates) along with water. Less energy is released.
  3. Why is CO dangerous?
    Carbon monoxide binds with very high affinity to haemoglobin, displacing oxygen and preventing oxygen transport. It is colourless and odourless.
  4. How is SO₂ produced from fuels?
    From sulphur impurities in fossil fuels. SO₂ dissolves in rainwater to form sulphurous/sulphuric acid (acid rain).
  5. Define specific energy.
    Energy released per unit mass of fuel (kJ kg⁻¹ or MJ kg⁻¹).
  6. Define energy density.
    Energy released per unit volume of fuel (kJ dm⁻³).
  7. Which fuel has the highest specific energy?
    Hydrogen (approximately 142 MJ kg⁻¹), but it has very low energy density by volume because it is a gas.
  8. How is bioethanol produced?
    By fermentation of sugars (from sugarcane/corn) using yeast: C₆H₁₂O₆ → 2C₂H₅OH + 2CO₂
  9. What is transesterification?
    The reaction of vegetable oils/fats with methanol (+ base catalyst) to produce biodiesel (FAME) and glycerol.
  10. Are biofuels truly carbon neutral?
    In theory yes (CO₂ absorbed in growth = CO₂ released in combustion), but in practice NO - farming, processing, and transport all require energy.
  11. Write the half-equations for a hydrogen fuel cell.
    Anode: H₂ → 2H⁺ + 2e⁻ | Cathode: O₂ + 4H⁺ + 4e⁻ → 2H₂O | Overall: 2H₂ + O₂ → 2H₂O
  12. Give two disadvantages of hydrogen fuel cells.
    1. Difficult to store H₂ (low energy density by volume, needs high pressure or cryogenic tanks). 2. Most H₂ is currently made from fossil fuels (steam reforming).
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