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Section 1 Flashcards

Test yourself on the Principles of Chemistry with these interactive flashcards. Click each card to reveal the answer.

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These flashcards cover all key concepts in Section 1. Test yourself using the active recall decks below to solidify your understanding of basic chemistry principles.

States of Matter & Solubility

States of Matter: read all 8 questions and answers
  1. Describe the arrangement and movement of particles in a solid.
    Particles are arranged in a regular, tightly packed lattice structure and vibrate about fixed positions.
  2. Describe the arrangement and movement of particles in a liquid.
    Particles are closely packed but arranged randomly, and they can slide past one another and flow.
  3. Describe the arrangement and movement of particles in a gas.
    Particles are widely spaced, arranged randomly, and move rapidly in all directions at high speeds.
  4. Explain why the temperature remains constant during a change of state.
    Because the thermal energy supplied is used to overcome and break the forces holding the particles together, rather than increasing their kinetic energy.
  5. What is diffusion?
    The net movement of particles from an area of higher concentration to an area of lower concentration down a concentration gradient, due to their random motion.
  6. In the ammonia and hydrogen chloride diffusion experiment, why does the white ring form closer to the HCl end?
    Ammonia has a lower relative molecular mass (\(M_{\text{r}} = 17\)) than hydrogen chloride (\(M_{\text{r}} = 36.5\)), so ammonia gas diffuses faster and travels further in the same time.
  7. Define solubility.
    The maximum mass of solute in grams that can dissolve in 100 grams of solvent at a specific temperature.
  8. What is a saturated solution?
    A solution containing the maximum mass of dissolved solute at a specific temperature, where no more solute can dissolve.

Atomic Structure & Periodic Table

Atomic Structure & Periodic Table: read all 7 questions and answers
  1. Define the terms element, compound, and mixture.
    Element: a substance made of only one type of atom. Compound: two or more elements chemically combined in fixed proportions. Mixture: two or more substances not chemically combined.
  2. What are the relative mass and charge of a proton, neutron, and electron?
    Proton: mass = 1, charge = +1. Neutron: mass = 1, charge = 0. Electron: mass = 1/1836 (approx. 0), charge = -1.
  3. Define atomic number and mass number.
    Atomic number: the number of protons in the nucleus of an atom. Mass number: the total number of protons and neutrons in the nucleus.
  4. What are isotopes?
    Atoms of the same element with the same number of protons but different numbers of neutrons.
  5. Define relative atomic mass (\(A_{\text{r}}\)).
    The weighted average mass of an atom of an element compared with 1/12th of the mass of a carbon-12 atom.
  6. How do you calculate \(A_{\text{r}}\) from isotopic abundances?
    \(A_{\text{r}} = \frac{(\text{mass}_1 \times \%_1) + (\text{mass}_2 \times \%_2)}{100}\).
  7. How is the periodic table arranged?
    In order of increasing atomic (proton) number. Elements in the same group have the same number of outer-shell electrons.

Formulae, Equations & Calculations

Chemical Calculations: read all 5 questions and answers
  1. What is the formula relating moles, mass, and \(M_{\text{r}}\) ?
    \(\text{Moles} = \frac{\text{Mass (g)}}{M_{\text{r}}\text{ (or } A_{\text{r}}\text{)}}\).
  2. Define empirical formula and molecular formula.
    Empirical formula: the simplest whole-number ratio of atoms of each element in a compound. Molecular formula: the actual number of atoms of each element in a molecule.
  3. How do you calculate the percentage yield?
    Percentage yield = (Actual yield / Theoretical yield) ×100.
  4. What is Avogadro's law for gas volumes?
    Equal volumes of gases at the same temperature and pressure contain equal numbers of molecules. One mole of any gas occupies 24 dm³ (24000 cm³) at room temperature and pressure (RTP).
  5. What is the formula relating moles, concentration, and volume of a solution?
    Moles=Concentration (mol/dm³) × Volume (dm³). (Volume in dm³ = volume in cm³ / 1000).

Bonding & Electrolysis

Bonding & Electrolysis: read all 7 questions and answers
  1. How is an ionic bond formed?
    By the electrostatic attraction between oppositely charged ions, formed by the transfer of electrons from a metal to a non-metal.
  2. Explain why ionic compounds have high melting and boiling points.
    They have a giant ionic lattice held together by strong electrostatic attractions between oppositely charged ions, requiring large amounts of energy to overcome.
  3. How is a covalent bond formed?
    By the electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms.
  4. Explain why simple molecular substances have low boiling points, whereas giant covalent substances have high melting points.
    Simple molecular substances have weak intermolecular forces between molecules that require little energy to break. Giant covalent substances contain many strong covalent bonds throughout a giant lattice that require massive energy to break.
  5. Explain why metals are malleable and conduct electricity.
    Malleable because the layers of metal ions can slide over one another without breaking the metallic bond. Conduct electricity because they contain a sea of delocalised electrons that are free to move and carry charge.
  6. Define electrolysis.
    The decomposition of an electrolyte by passing an electric current through it.
  7. During the electrolysis of aqueous solutions, what is formed at the anode and cathode?
    Cathode (negative): hydrogen gas is formed unless the metal ion is less reactive than hydrogen (e.g. copper). Anode (positive): oxygen gas is formed unless halide ions (Cl⁻, Br⁻, I⁻) are present at high concentration, in which case the halogen is formed.
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