IB ChemistryStructure 33.23.2.3
3.2.3

Homologous Series

A family of compounds where successive members differ by \(-CH_2-\).

Key Characteristics

  • Same Functional Group: Determines the chemical properties.
  • Same General Formula: A mathematical formula for the entire series.
  • Differ by \(-CH_2-\): Each successive member adds one methylene unit.
  • Gradation in Physical Properties: Predictable trends in boiling point, density, etc.
  • Similar Chemical Properties: They react in similar ways.

General Formulas

Alkanes

\(C_nH_{2n+2}\)

Alkenes

\(C_nH_{2n}\)

Alkynes

\(C_nH_{2n-2}\)

Alcohols

\(C_nH_{2n+1}OH\)

Carboxylic Acids

\(C_nH_{2n+1}COOH\)

Aldehydes

\(C_nH_{2n+1}CHO\)