IB ChemistryStructure 33.23.2.1
3.2.1

Types of Formula

Empirical, molecular, structural, condensed, and skeletal. Different ways to represent the same molecule.

Formula Type Shows Ethanol Example
Empirical Simplest whole-number ratio C₂H₆O
Molecular Actual number of each atom C₂H₆O
Full structural Every bond drawn explicitly H-C-C-O-H (with all H)
Condensed Groups written sequentially CH₃CH₂OH
Skeletal C-C backbone as zig-zag; H on C omitted Line with -OH at end

⚠️ Examiner Trap

In a full structural formula, every single bond must be drawn, including those within functional groups. Writing "-OH" instead of "-O-H" will lose the mark. If the question says "structural formula," draw all bonds.

⚠️ Hidden Hydrogens in Skeletal Formulas

When interpreting skeletal structures, remember carbon always has 4 bonds. Count the drawn bonds at each vertex/end and add implicit H atoms to reach 4. Forgetting this leads to wrong molecular formulas.

⚠️ Functional Group Connectivity

Draw -COOH connected through the carbon atom, not through the H. Writing the carboxylic acid group backwards (HOOC-) or connecting through the wrong atom loses marks. The same applies to alcohols: write C-O-H, never C-HO.

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