IB ChemistryStructure 22.22.2.7
2.2.7

Giant Covalent Structures

Silicon, Silicon Dioxide, and Carbon Allotropes.

Carbon Allotropes

Feature Diamond Graphite Graphene C₆₀ Fullerene
Structure 3D Network Layered Single Sheet Sphere
Bonds per C 4 3 3 3
Conductivity No Yes Yes (Very High) Semi
Hardness Very Hard Soft (Layers slide) Very Strong Moderate

Silicon Structures

Silicon (Si)

Tetrahedral lattice structure identical to Diamond. Each Si bonded to 4 others. Semiconductor — used in microchips.

Silicon Dioxide (SiO₂)

Giant covalent network (Sand/Quartz). Each Si bonded to 4 O, each O bonded to 2 Si. Strong, high MP, non-conductive.

Why does Graphite Conduct?

Each carbon in Graphite uses only 3 of its 4 valence electrons for bonding. The 4th electron is delocalized across the entire layer — creating mobile charge carriers (like a metal).

Think About It

Both diamond and SiO₂ are giant covalent structures with high melting points. But diamond is used as a cutting tool and SiO₂ (sand) is not. Why?

Diamond has each carbon bonded to 4 others in a uniform 3D tetrahedral lattice — making it the hardest known natural substance. SiO₂ also has a 3D network, but the Si–O bonds are longer and the lattice arrangement is less compact, so it is hard but not as hard as diamond. Crucially, diamond's uniform C–C bonding gives it no weak points.

← 2.2.6 Molecular Polarity 2.2.8 Intermolecular Forces →