IB Chemistry R1.3 R1.3.4
R1.3.4

Hydrogen Fuel Cells

A fuel cell converts chemical energy directly into electrical energy through a continuous electrochemical reaction, without combustion.

How It Works

In a hydrogen–oxygen fuel cell (PEM type):

  • Anode (−): H₂ → 2H⁺ + 2e⁻  (oxidation)
  • Cathode (+): O₂ + 4H⁺ + 4e⁻ → 2H₂O  (reduction)
  • Overall: 2H₂ + O₂ → 2H₂O

PEM Hydrogen Fuel Cell

PEM Membrane ANODE (−) H₂ enters H₂ → 2H⁺ + 2e⁻ CATHODE (+) O₂ enters O₂ + 4H⁺ + 4e⁻ → 2H₂O H⁺ ions e⁻ flow (external circuit) W H₂O out

Advantages vs Disadvantages

Advantages

  • Only product is water — zero emissions
  • Higher efficiency than combustion engines (~60% vs ~25%)
  • Quiet operation, no moving parts
  • Hydrogen has the highest specific energy

Disadvantages

  • H₂ storage is difficult (low energy density by volume)
  • Most H₂ currently from steam reforming of natural gas (not green)
  • Expensive platinum catalysts
  • Lack of refuelling infrastructure

Think About It

If hydrogen is produced by electrolysis using solar energy, is the fuel cell truly "zero carbon"?

Yes — green hydrogen from renewable electrolysis creates no net CO₂. However, the production of the solar panels and fuel cell components still has an embedded carbon footprint (lifecycle analysis).

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