Topic 9 of 10

Chemistry of the Atmosphere

Trace the evolution of Earth's atmosphere from volcanic beginnings to today — and understand the science behind greenhouse gases, climate change, and air quality.

AQA Hub Topic 9

The Current Atmosphere

The proportions of gases in the Earth's atmosphere today have been relatively stable for about 200 million years:

  • Nitrogen (N₂): ~78%
  • Oxygen (O₂): ~21%
  • Argon (Ar): ~0.9%
  • Carbon dioxide (CO₂): ~0.04%
  • Water vapour and other trace gases: very small amounts
These percentages have been broadly stable for 200 million years. However, CO₂ levels have been rising significantly since the Industrial Revolution.

The Early Atmosphere

For the first billion years of Earth's existence, the atmosphere was very different. Intense volcanic activity released gases that formed the early atmosphere.

Composition of the Early Atmosphere

  • Mainly carbon dioxide (CO₂) — similar to Mars and Venus today.
  • Very little or no oxygen.
  • Water vapour (from volcanic eruptions), which later condensed to form the oceans.
  • Smaller amounts of methane and ammonia.
We can't be 100% certain about the early atmosphere because there were no direct measurements. Scientists use evidence from rocks, fossils, and comparing with other planets to estimate.

How Oxygen Increased

Stage 1: Photosynthesis by Early Life Forms

Around 2.7 billion years ago, simple organisms like cyanobacteria (algae) evolved. They photosynthesised, absorbing CO₂ and releasing O₂.

6CO₂ + 6H₂O → C₆H₁₂O₆ + 6O₂

Over hundreds of millions of years, this gradually increased oxygen levels.

Stage 2: Reducing CO₂

Carbon dioxide was removed from the atmosphere by:

  • Dissolving in the oceans — forming carbonate sedimentary rocks (limestone) and by marine organisms incorporating it into shells.
  • Photosynthesis — locked up carbon in biomass.
  • Formation of fossil fuels — dead organisms were buried, compressed, and transformed into coal, oil, and gas over millions of years.

Greenhouse Gases & the Greenhouse Effect

Some gases in the atmosphere absorb heat radiation (infrared) emitted by the Earth's surface and re-radiate it in all directions, including back towards the surface. This is the greenhouse effect, and it keeps the Earth warm enough to support life.

The Main Greenhouse Gases

  • Carbon dioxide (CO₂): From burning fossil fuels, deforestation.
  • Methane (CH₄): From cattle farming, rice paddies, landfill decomposition.
  • Water vapour (H₂O): Natural evaporation.
Without the greenhouse effect, Earth would be too cold to support life. The problem is the enhanced greenhouse effect — extra greenhouse gases trap more heat.

Climate Change

Since the Industrial Revolution (mid-1800s), human activities have significantly increased the concentration of greenhouse gases. This enhanced greenhouse effect is causing global temperatures to rise — known as global warming.

Consequences of Climate Change

  • Polar ice caps melting → sea level rise → flooding of low-lying areas
  • More extreme weather events (droughts, floods, storms)
  • Changes to ecosystems and habitats
  • Impact on agriculture and food production
  • Migration and redistribution of species

Why is There a Debate?

While the vast majority of scientists agree that human activity is the main cause, the evidence involves very complex climate models and long-term data. Media, politics, and economics also influence public perception.

In the exam, acknowledge the scientific consensus but mention that climate models have limitations and that peer review is vital for assessing climate data.

Carbon Footprint

A carbon footprint is the total amount of carbon dioxide and other greenhouse gases emitted over the full life cycle of a product, service, or event.

Ways to Reduce Carbon Footprint

  • Using renewable energy sources (solar, wind, tidal) instead of fossil fuels.
  • Improving energy efficiency of buildings and vehicles.
  • Carbon capture and storage (CCS) technology.
  • Reducing waste, reusing materials, and recycling.
  • Planting trees to absorb CO₂.
  • Using public transport or cycling instead of driving.
Be able to discuss why complete reduction of carbon footprint is difficult — it requires lifestyle changes, is economically challenging, and some processes currently have no alternative to fossil fuels.

Atmospheric Pollutants

Burning fossil fuels releases several harmful pollutants:

Carbon Monoxide (CO)

Produced by incomplete combustion. Colourless and odourless, making it very dangerous. It binds to haemoglobin, preventing blood from carrying oxygen.

Sulfur Dioxide (SO₂)

Produced from burning fuels containing sulfur impurities. Dissolves in water in the atmosphere to form acid rain, which damages buildings (especially limestone/marble), kills aquatic life, and damages plants.

Nitrogen Oxides (NOₓ)

Formed when nitrogen and oxygen in the air react at the high temperatures inside car engines. Also contributes to acid rain and photochemical smog.

Particulates (Soot)

Tiny particles of unburned carbon from incomplete combustion. Cause respiratory problems, darken buildings, and contribute to global dimming (reflecting sunlight back to space).

Catalytic converters in car exhausts reduce emissions of CO and NOₓ by converting them into less harmful gases: CO → CO₂ and NOₓ → N₂.